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81.
Chih‐Feng Wang Shih‐Feng Chiou Fu‐Hsiang Ko Cheng‐Tung Chou Han‐Ching Lin Chih‐Feng Huang Feng‐Chih Chang 《Macromolecular rapid communications》2006,27(5):333-337
Summary: In this study, a method for producing super‐amphiphobic surfaces through plasma modification of benzoxazine films is presented. Microroughening and fluorination of the benzoxazine films occurs during the plasma treatment process and a rugged surface with a micro/nano binary structure is formed. The combined effect of low surface energy and substrate roughness results in high advancing contact angles (157° for water, 152° for diiodomethane) and low contact angle hysteresis.
82.
Tsu Hsu Ting‐Yueh Tsai Ya‐Ju Tseng Mei‐Chun Chiou Cheng‐Tai Lu Yu‐Sheng Chao Weir‐Torn Jiaang 《中国化学会会志》2011,58(1):108-117
A novel five‐step synthesis of Boc‐3,3‐dimethylglutamic acid α‐ethyl ester 11 is reported. All the steps are high yielding and simple to carry out. By use of the 3,3‐dimethylglutamic acid building block, we successfully discovered a novel class of DPP‐IV inhibitors, Glu‐Pro‐Nitrile dipeptide mimics 2 , with high potency (IC50 < 40 nM). The consequence of 3,3‐dimethyl substituent on the rate of intramolecular cyclization between N‐terminal amine and 5‐position amide bond in different buffer solutions was also evaluated. 相似文献
83.
The problem of laminar, natural convection flow over a slender frustum of a cone is treated in this paper. The governing differential equations are solved by a combination of quasi-linearization and finite-difference methods. Numerical solutions are obtained for Pr=0.7 and for a range of values of the transverse curvature parameter. It is shown that the effect of transverse curvature is of great significance in such flows.
Nomenclature f dependent variable, defined in Eq. (7) - g dependent variable, defined in Eq. (7) - ge gravitational acceleration - h heat transfer coefficient, or -grid - k heat conductivity, or -grid - L characteristic length - Nu Nusselt number - Pr Prandtl number - r radial distance from the axis of the cone - R transverse curvature effect ratio, defined in Eq. (23) - Re Reynold number - T temperature - u, v velocity components in the x- and y-directions, respectively - x, y rectangular coordinates Greek letters dimensionless temperature, definedinEq. (4) - bulk modulus - cone angle - dynamic viscosity - stream function - , independent variable, defined in (7) - transverse curvature parameter 相似文献
Laminare natürliche Konvektion an einem dünnen, senkrechten Kegelstumpf
Zusammenfassung In diesem Bericht ist das Problem der laminaren natürlichen Konvektionsströmung an einem dünnen Kegelstumpf behandelt. Die maßgebliche Differentialgleichung ist durch eine Verbindung von Quasilinearisation und Differenzenverfahren gelöst. Eine numerische Lösung für Pr=0.7 wird für verschiedene Werte eines Krümmungsparameters angegeben. Es ist gezeigt, daß in solchen Strömungen dieser Krümmungsparameter eine große Bedeutung besitzt.
Nomenclature f dependent variable, defined in Eq. (7) - g dependent variable, defined in Eq. (7) - ge gravitational acceleration - h heat transfer coefficient, or -grid - k heat conductivity, or -grid - L characteristic length - Nu Nusselt number - Pr Prandtl number - r radial distance from the axis of the cone - R transverse curvature effect ratio, defined in Eq. (23) - Re Reynold number - T temperature - u, v velocity components in the x- and y-directions, respectively - x, y rectangular coordinates Greek letters dimensionless temperature, definedinEq. (4) - bulk modulus - cone angle - dynamic viscosity - stream function - , independent variable, defined in (7) - transverse curvature parameter 相似文献
84.
85.
Heat and Mass Transfer - The problem of two-dimensional, steady film condensation on a finite-size, isothermal horizontal disk is studied for the case in which a cold plate faces upwards. The... 相似文献
86.
Meng-Jhen Chiou Yu-Ching Lin Takahito Ono Masayoshi Esashi Sih-Ling Yeh Tsung-Tsong Wu 《Ultrasonics》2014
This paper presents results on the numerical and experimental studies of focusing and waveguiding of the lowest anti-symmetric Lamb wave in micro-fabricated piezoelectric phononic plates. The phononic structure was based on an AT-cut quartz plate and consisted of a gradient-index phononic crystal (GRIN PC) lens and a linear phononic plate waveguide. The band structures of the square-latticed AT-cut quartz phononic crystal plates with different filling ratios were analyzed using the finite element method. The design of a GRIN PC plate lens which is attached with a linear phononic plate waveguide is proposed. In designing the waveguide, propagation modes in square-latticed PC plates with different waveguide widths were studied and the results were served for the experimental design. In the micro-fabrication, deep reactive ion etching (Deep-RIE) process with a laboratory-made etcher was utilized to fabricate both the GRIN PC plate lens and the linear phononic waveguide on an 80 μm thick AT-cut quartz plate. Interdigital transducers were fabricated directly on the quartz plate to generate the lowest anti-symmetric Lamb waves. A vibro-meter was used to detect the wave fields and the measured results on the focusing and waveguiding of the piezoelectric GRIN PC lens and waveguide are in good accordance with the numerical predictions. The results of this study may serve as a basis for developing an active micro plate lens and related devices. 相似文献
87.
Chao-Jung Chen Chien-Chen Lai Mei-Chun Tseng Yu-Ching Liu Yu-Huei Liu Liang-Wei Chiou Fuu-Jen Tsai 《Analytica chimica acta》2014
The phosphorylation of proteins is a major post-translational modification that is required for the regulation of many cellular processes and activities. Mass spectrometry signals of low-abundance phosphorylated peptides are commonly suppressed by the presence of abundant non-phosphorylated peptides. Therefore, one of the major challenges in the detection of low-abundance phosphopeptides is their enrichment from complex peptide mixtures. Titanium dioxide (TiO2) has been proven to be a highly efficient approach for phosphopeptide enrichment and is widely applied. In this study, a novel TiO2 plate was developed by coating TiO2 particles onto polydimethylsiloxane (PDMS)-coated MALDI plates, glass, or plastic substrates. The TiO2-PDMS plate (TP plate) could be used for on-target MALDI-TOF analysis, or as a purification plate on which phosphopeptides were eluted out and subjected to MALDI-TOF or nanoLC-MS/MS analysis. The detection limit of the TP plate was ∼10-folds lower than that of a TiO2-packed tip approach. The capacity of the ∼2.5 mm diameter TiO2 spots was estimated to be ∼10 μg of β-casein. Following TiO2 plate enrichment of SCC4 cell lysate digests and nanoLC-MS/MS analysis, ∼82% of the detected proteins were phosphorylated, illustrating the sensitivity and effectiveness of the TP plate for phosphoproteomic study. 相似文献
88.
The purpose of this study was to prospectively compare noninvasive, quantitative measures of vascularity obtained from four contrast enhanced ultrasound (US) techniques to four invasive immunohistochemical markers of tumor angiogenesis in a large group of murine xenografts. Glioma (C6) or breast cancer (NMU) cells were implanted in 144 rats. The contrast agent Optison (GE Healthcare, Princeton, NJ) was injected in a tail vein (dose: 0.4 ml/kg). Power Doppler imaging (PDI), pulse-subtraction harmonic imaging (PSHI), flash-echo imaging (FEI), and Microflow imaging (MFI; a technique creating maximum intensity projection images over time) was performed with an Aplio scanner (Toshiba America Medical Systems, Tustin, CA) and a 7.5 MHz linear array. Fractional tumor neovascularity was calculated from digital clips of contrast US, while the relative area stained was calculated from specimens. Results were compared using a factorial, repeated measures ANOVA, linear regression and z-tests. The tortuous morphology of tumor neovessels was visualized better with MFI than with the other US modes. Cell line, implantation method and contrast US imaging technique were significant parameters in the ANOVA model (p < 0.05). The strongest correlation determined by linear regression in the C6 model was between PSHI and percent area stained with CD31 (r = 0.37, p < 0.0001). In the NMU model the strongest correlation was between FEI and COX-2 (r = 0.46, p < 0.0001). There were no statistically significant differences between correlations obtained with the various US methods (p > 0.05). In conclusion, the largest study of contrast US of murine xenografts to date has been conducted and quantitative contrast enhanced US measures of tumor neovascularity in glioma and breast cancer xenograft models appear to provide a noninvasive marker for angiogenesis; although the best method for monitoring angiogenesis was not conclusively established. 相似文献
89.
In this paper, effects of ethylene glycol (EG) and indium tin oxide (ITO) solution on the morphology, porosity, and roughness of TiO2 film prepared by sol‐gel process were investigated and discussed. Initially, the addition of EG were used to control the viscosity of the solution and it was found to increase the pore size of TiO2 film. The various TiO2 films were investigated and characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM) and then assembled to dye‐sensitized solar cell (DSSC) to measure the photoelectric conversion efficiency. The optimum efficiencies of 1.32% with Jsc and Voc of 2.99 mA/cm2 and 0.80 V, respectively, were obtained by the TiO2 film prepared from a solution containing 20 wt% EG. 相似文献
90.
We have demonstrated InGaAsN/ GaAs single quantum well (SQW) lasers grown by MOCVD using TBAs and DMHy sources. For un-buffer-strained InGaAsN/ GaAs system, our SQW lasers of 1.3 m m range is among the best in terms of transparency and threshold current density. 相似文献